本篇論文對二硫氨基甲酸鹽類（Dithiocarbamates）、銅起始物[Cu(CH3CN)4](PF6)、苯乙炔（Phenylethynide）、以及氫負離子（Hydride）合成雙配體多核奈米團簇，進行結構研究與討論。
主要的實驗以參考Kiran博士後研究員，透過[Cu28(H)15(S2CNR2)12](PF6)多核銅金屬奈米團簇，加入炔基配體進行脫氫反應，合成出全新的雙配體多核金屬奈米團簇[Cu13(S2CNR2)6(C2Ph)4](PF6) (R=nBu)，過程發現[Cu15(H)2(S2CNR2)6(C2Ph)6](PF6)結構的存在，本實驗經由Cu(I)合成的方式，合成出[Cu15(H)2(S2CNR2)6(C2Ph)6](PF6) (R=nPr、iBu、nBu) 再以1H、2H、13C、31P{1H}、ESI-MS、UV-vis、X-ray單晶繞射鑑定出化合物，在本篇論文中也會進行一系列比較探討。

目錄
摘要............................ I
目錄 ........................... II
ㄧ、緒論 ........................ 1
二、實驗部分 .................... 7
三、結果與討論 .................. 23
四、結論 ........................ 61
五、參考文獻 .................... 63
附 錄 ........................ 65

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