染料敏化太陽能電池也稱為第三代奈米薄膜太陽能電池，由於電池原料成本低且取得容易、製程簡單，只需要簡易設備即可完成，並具備有透光、半透明特性以及可撓性質，可廣泛應用於日常生活當中，如小型3C產品、建築玻璃等。鈣鈦礦太陽能電池具有良好的吸光特性以及高轉換效率之表現，幾年之內光電轉化效率從3.8%提高到認證的22.1%，與傳統矽晶太陽能電池相比，材料成本、製程設備與製程時間更低且迅速，吸引眾多科研者投入研究，為現在一大熱門議題。
本研究透過材料以及元件特性分析，探討不同材料及製程對於染料敏化太陽能電池及鈣鈦礦太陽能電池所產生的影響。本研究可分為三個部分：一、鈣鈦礦太陽能電池之電子傳輸層PC60BM膜厚轉速之比較，實驗結果顯示，在轉速1750rpm時，元件能達到12.36% 效率。在1750rpm時，PC60BM電子傳輸層能夠達到最平整且最具有包覆性的薄膜，有利於電子傳輸通過。二、使用四種不同有機溶劑：甲苯(MB)、三氯甲烷(CF)、氯苯(CB)、鄰二氯苯(DCB)，添加於鈣鈦礦主動層，使鈣鈦礦表面結晶程度改變。實驗結果顯示，當使用甲苯(MB)時能達到最好的表面結晶均勻程度及表面包覆程度，元件效率最高可達到約11.01%。三、使用不同燒結溫度的GO/Mn，再與PEDOT高分子混合，形成複合材料，以取代傳統染料敏化太陽能電池白金(Pt)對電極，實驗結果顯示，使用PEDOT/GO/Mn 300°C複合材料作為對電極，元件效率可達到7.69%，優於傳統白金對電極之電池轉換效率(7.34%)。

Dye-sensitized solar cells are known as the third-generation nano thin-film solar cells. For DSSCs, the materials are inexpensive and the fabrication processes are simple, only need simple equipment to make a solar cell. Dye-sensitized solar cells have the advantages of light transparency and flexibility. They can be widely used in daily life, such as small 3C products, glass of buildings. Perovskite solar cells have good light absorption characteristics and high conversion efficiency. Within a few years, the conversion efficiency increased from 3.8% to 22.1%. Material costs and fabrication time are lower than traditional silicon solar cells. Recently, perovskite solar cells have been a hot research topic.
This study uses material and device characteristics analysis to apply different materials and process conditions for dye-sensitized solar cells and perovskite solar cells. The experimental part can be divided into three parts. First, the spin coating speed of the electron transport layer PC60BM for perovskite solar cell was studied. The results showed that the highest PSC efficiency of about 12.36% was obtained at the spin coating speed of 1750 rpm. At 1750 rpm, the film of PC60BM can achieve a flat and coveraged film, which can enhance the electron transport properties. Second, four different organic solvents including toluene (MB), chloroform (CF), chlorobenzene (CB), and orthodichlorobenzene (DCB) were separately added to the perovskite active layer. When toluene (MB) was used, the best surface crystal uniformity and surface coverage can be achieved, and the device efficiency can reach up to about 11%. Third, polymer and GO/Mn composite materials were used as counter electrodes for DSSCs. PEDOT/GO/Mn composites were used to replace the traditional platinum (Pt) counter electrode. The results showed that DSSCs with PEDOT/GO/Mn 300°C counter electrode can achieve the maximum conversion efficiency of 7.69%, which was higher than that of the DSSCs using traditional platinum electrode.

致謝 III
摘要 V
Abstract VII
目錄 IX
圖目錄 XIII
表目錄 XVII
第一章 緒論 1
1.1 前言 1
1.1.1 能源現況 1
1.1.2 太陽能 4
1.2 太陽能電池 7
1.2.1太陽能電池種類與發展 7
1.2.2 染料敏化太陽能電池 9
1.2.3 鈣鈦礦太陽能電池 13
1.3 實驗儀器與研究原理 18
太陽光模擬器 (Solar Simulator) 18
電化學分析儀(EIS) 21
外部量子效率量測儀 (External Quantum Efficiency Measurement System) 23
場發射掃描式電子顯微鏡 (Field-emission Scanning Electron Microscope) 25
能量色散X光譜儀(Energy dispersive spectrometers, EDS) 25
原子力顯微鏡(Atomic Force Microscope) 26
X光繞射分析儀 (X-Ray Diffractometer) 28
X光光電子能譜儀 (X-ray Photoelectron Spectrometer) 29
紫外光/可見光光譜儀(UV/VIS Spectrometer) 29
1.4 參考文獻 31
第二章 鈣鈦礦太陽能電池之電子傳輸層PC60BM轉速比較 35
2.1前言 35
2.2 實驗方法 37
2.2.1 材料製備 37
2.2.2 元件製作 37
2.3 結果與討論 40
2.3.1 材料特性分析 40
表面形貌分析 40
元素結構分析 50
光學特性分析 55
2.3.2 元件特性分析 56
J-V Curve 分析 56
外部量子效率分析 58
老化實驗分析 59
2.4 結論 61
2.5參考文獻 63
第三章 鈣鈦礦太陽能電池主動層添加不同溶劑比較 65
3.1前言 65
3.2 實驗方法 66
3.2.1 材料製備 66
3.2.2 元件製作 66
3.3 結果與討論 69
3.3.1 材料特性分析 69
表面形貌分析 69
元素結構分析 74
光學特性分析 78
3.3.2元件特性分析 80
J-V Curve 分析 80
外部量子效率分析 82
電化學阻抗頻譜分析 83
3.4 結論 84
3.5參考文獻 86
第四章 PEDOT/石墨烯/錳大環錯合物複合材料於染料敏化太陽能電池對電極之研究 87
4.1前言 87
4.2 實驗方法 88
4.2.1材料製備 88
3.2.2 元件製作 90
4.3 結果與討論 93
4.3.1 材料特性分析 93
表面形貌分析 93
元素結構分析 99
電化學循環伏安分析 105
4.3.2元件特性分析 106
J-V Curve 分析 106
外部量子效率分析 108
電化學阻抗頻譜分析 109
4.4 結論 110
4.5參考文獻 111
第五章 總結論 113

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