1.學生成功使用one-pot synthesis 成功合成出含有Pd摻雜的銀奈米團簇PdAg20[S2P(OiPr)2]12，而且可以輕易地利用配體置換的方式，合成出由二硒磷酸配位基保護含有Pd摻雜的銀奈米團簇PdAg20[Se2P(OnPr)2]12，同時還有一種高發射性的8電子合金PdAg20{S2P(C6H5)2}12，亦可使用配體置換的方式單離出來。

2.利用所成功合成出含有Pd摻雜的銀奈米團簇作為催化劑，進行Sonogashira coupling以及Glaser coupling，並通過各種條件的試驗，能有效的提高產率。

摘要 I
一、緒論 1
二、實驗部分 7
2.1儀器藥品 7
2.2實驗步驟 10
2.2.1 [NH4][S2P(OiPr)2] 10
2.2.2 [NH4][Se2P(OnPr)2] 11
2.2.4 Pd[S2P(OiPr)2]2 12
2.2.5 PdAg20[S2P(OiPr)2]12 13
2.2.6 PdAg20[Se2P(OnPr)2]12 14
2.2.7 PdAg20{S2P(C6H5)2}12 15
2.2.8 non-solvent Sonogashira coupling 16
2.2.9 sonogashira coupling 17
2.2.10 glaser coupling 18
三.結果與討論 19
3.1 Pd-Ag 合金奈米糰簇之合成 19
3.1.1 PdAg20[S2P(OiPr)2]的合成 19
3.1.2PdAg20[Se2P(OnPr)2]12的合成 21
3.1.3 PdAg20{S2P(C6H5)2}12的合成 21
3.2 Pd-Ag 合金奈米糰簇之晶體結構分析 22
3.2.1 PdAg20[S2P(OiPr)2]12之結構分析 22
3.2.2 PdAg20[Se2P(OnPr)2]12之結構分析 24
3.3 Pd-Ag 合金奈米糰簇之光譜分析 26
3.3.1.NMR 26
3.3.2 質譜 29
3.3.3吸收光譜與放光光譜 32
3.4 催化性質 37
3.4.1 sonogashira coupling 37
3.4.2 Glaser coupling 44
四、結論 65
五、參考資料 67

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