本實驗透過使用較親水性的離子液體Bmim［BF4］，及較疏水性的Bmim［PF6］，分別與高分子Tween80以各種濃度均勻混合，在常壓下使用傅立葉紅外光譜儀(FT-IR)做掃描，並分析其光譜圖隨濃度改變，相較於純化合物時分別有何趨勢，且比較當離子液體的陰離子不同時，對高分子的結合力又有何影響，還使用了另一高分子EPM(聚乙烯丙烯)與離子液體Bmim［BF4］混合，做一個高分子不同時的對照組，分析各組合之間的作用力變化。

最後再使用鑽石砧，對純離子液體、純高分子，以及其混合物施加各種不同壓力，隨著壓力漸漸增加，觀察它們的紅外光譜訊號變化，分析圖譜峰值受到擾動是因何種作用力影響，並討論各混合物間相互作用力的強度，以及其未來在各行業的應用性。

In this experiment, the hydrophilic ionic liquid Bmim[BF4] and the hydrophobic Bmim[PF6] were used to uniformly mix with the polymer Tween80 at various concentrations, respectively. Fourier-transform infrared spectroscopy (FT-IR) was used to scan and analyze how the spectrum changes with concentration compared to pure compounds under normal pressure. Compare when the anions of the ionic liquid are different, what is the effect on the binding force of the polymer. Another polymer EPM was also used to mix with the ionic liquid Bmim [BF4], and a control group with different polymers was used to analyze the change of the force between the combinations. Finally, diamonds are used to apply various pressures to pure ionic liquids, pure polymers, and mixtures. As the pressure gradually increased, observe the changes in their infrared spectral signals. Analyze the force that causes the peaks of the spectrum to be disturbed, and discuss the strength of the interaction between the mixtures and its future applicability in various industries.

1. 論文大綱 3
2. 序論 11
3. 實驗 17
3.1 實驗藥品 17
3.1.1 離子液體 17
3.1.2 高分子聚合物 17
3.2 實驗儀器 18
3.3 實驗步驟 19
3.3.1 實驗方法 19
3.3.2 樣品配製 20
4. 結果討論 23
4.1 常壓實驗 23
4.1.1 純IL與高分子 23
4.1.2 離子液體Bmim［BF4］與高分子Tween 80 25
4.1.3 離子液體Bmim［PF6］與高分子Tween 80 25
4.2 常壓峰值分析 28
4.2.1 離子液體Bmim［BF4］與高分子Tween 80 28
4.2.2 離子液體Bmim［PF6］與高分子Tween 80 31
4.2.3 離子液體Bmim［BF4］與高分子EPM 34
4.3 高壓實驗 36
4.3.1 高分子EPM 36
4.3.2高分子Tween 80 38
4.3.3 離子液體Bmim［BF4］ 40
4.3.4 離子液體Bmim［PF6］ 42
4.3.5 離子液體Bmim［BF4］與高分子EPM 44
4.3.6 離子液體Bmim［BF4］與高分子Tween 80 46
4.3.7 離子液體Bmim［PF6］與高分子Tween 80 49
4.4 高壓峰值分析 52
4.4.1 離子液體Bmim的C4,5吸收峰 52
4.4.2 離子液體Bmim的C2吸收峰值 56
4.4.3 高分子的不對稱C－H吸收峰 59
4.4.4 高分子的對稱C－H吸收峰 62
5. 結論 65
6. 參考文獻 67

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