由於近年來在學術界討論銀奈米團簇其特性以及基屬團簇的研究及合成奈米材料方面受到很大的關注，使團簇科學成為一個大家積極研究的領域，近幾年加入了超原子的概念。
在近期實驗室發表了關於[Pt2Ag33{S2P(OR)2}17] (R=nPr) 作為基礎，最近幾年裡，陸陸續續許多加入了第二種不同金屬在銀奈米團簇裡，發現可以改變物理及化學性質，所以近年來許多相關的研究越來越多。在這篇論文裡成功合成了(IrH2)2Ag31[S2P(OR)2]17及(IrH)2Ag33[S2P(OR)2]17的共結晶結構，並且也合成了氘的產物(Ir(D)2)2Ag31[S2P(OR)2]17及(Ir(D))2Ag33[S2P(OR)2]17，利用ESI-MS，UV-vis，X-ray等等方式來鑑定。

摘要 i
一、緒論 1
二、實驗部分 9
2.1儀器 9
2.2儀器 10
2.3實驗步驟 12
2.3.1 {(IrH2)2Ag31[S2P(OnPr)2]17}0.8及 {(IrH)2Ag33[S2P(OnPr)2]17}0.2的合成 12
2.3.2 {(Ir(D)2)2Ag31[S2P(OnPr)2]17}0.8及{(Ir(D))2Ag33[S2P(OnPr)2]17}0.2的合成 13
三、結果與討論 15
3.1 {(IrH2)2Ag31[S2P(OnPr)2]17}0.8及{(IrH)2Ag33[S2P(OnPr)2]17}0.2的合成 15
3.2 {(IrH2)2Ag31[S2P(OnPr)2]17}0.8及{(IrH)2Ag33[S2P(OnPr)2]17}0.2的結構 19
3.3 {(IrH2)2Ag31[S2P(OnPr)2]17}0.8及{(IrH)2Ag33[S2P(OnPr)2]17}0.2與[Pt2Ag33{S2P(OnPr)2}17]的結構比較 29
3.4 {(IrH2)2Ag31[S2P(OnPr)2]17}0.8及{(IrH)2Ag33[S2P(OnPr)2]17}0.2光譜 31
3.4.1常溫及變溫磷譜 31
3.4.2 室溫及變溫氫譜和氘譜 36
3.4.3 吸收光譜與螢光光譜與時間分辨光致發光光譜 40
3.4.4元素分析 43
四、結論 45
五、參考文獻 47

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