本論文透過紅外光譜實驗研究了奈米孔洞材料(PEEK)，此種薄膜在混合鈣鈦礦晶體(FAPbBr3)及離子液體([BMIM][BF4]、[BMIM][PF6]) 在不同壓力下之間的詳細作用力及相變化，其中在逐增壓力下能延緩FAPbBr3晶體產生相變化，且高壓的環境下FAPbBr3在PEEK奈米孔洞裡晶格排列比起純FAPbBr3晶體會更加緊密形成結構穩定的相，具有一定程度的穩定性，論文也顯示了PEEK混合兩種離子液體[BMIM][BF4]和[BMIM][PF6]在高壓環境下之間的作用力，藉以了解離子液體在奈米孔洞材料裡面的相變化，離子液體在PEEK的奈米孔洞之間可以看到一些作用力的發生，可以觀察到其中兩種不同性質的離子液體會與PEEK在不同壓力下產生不相同強度的作用力，導致其中相變化的差異性。

摘要 VII
目錄 IX
圖目錄 XIII
表目錄 XIX
1. 前言 1
1-1 1
1-2 1
2. 緒論 3
2-1 鈣鈦礦(perovskite) 3
2-2 高分子 5
2-3 離子液體 5
2-4 氫鍵與弱氫鍵 7
3. 實驗 9
3-1 儀器 9
3-1-1 IR 9
3-1-2 DAC 9
3-1-3 其他儀器 12
3-2 藥品 13
3-2-1 FAPbBr3製備 15
3-2-2 PEEK前處理 15
3-3 實驗步驟 16
3-3-1 常壓實驗 16
3-3-2 數據分析 18
4. 結果與討論 19
4-1 鈣鈦礦與高分子及單晶纖維的作用力 19
4-1-1 紅外光譜常壓實驗波數範圍落在2900-3500 cm-1 19
4-1-2 紅外光譜高壓實驗波數範圍落在2900-3500 cm-1 21
4-1-3 紅外光譜常壓實驗波數範圍落在1550-1800 cm-1 28
4-1-4 紅外光譜高壓實驗波數範圍落在1550-1800 cm-1 30
4-2 離子液體與高分子的作用力 38
4-2-1 [BMIM][BF4]與PEEK紅外光譜常壓實驗波數範圍落在2800-3300 cm-1 38
4-2-2 [BMIM][BF4]與PEEK紅外光譜高壓實驗波數範圍落在2800-3300 cm-1 40
4-2-3 [BMIM][BF4]與PEEK紅外光譜常壓實驗波數範圍落在700-1400 cm-1 46
4-2-4 [BMIM][BF4]與PEEK紅外光譜高壓實驗波數範圍落在700-1400 cm-1 48
4-2-5 [BMIM][PF6]與PEEK紅外光譜常壓實驗波數範圍落在2800-3300 cm-1 52
4-2-6 [BMIM][PF6]與PEEK紅外光譜高壓實驗波數範圍落在2800-3300 cm-1 54
4-2-7 [BMIM][PF6]與PEEK紅外光譜常壓實驗波數範圍落在700-1400 cm-1 60
4-2-8 [BMIM][PF6]與PEEK紅外光譜高壓實驗波數範圍落在700-1400 cm-1 62
5. 結論 66
6. Support information 67
7. 參考文獻 68

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