近年來我們都可以從媒體、氣象研究等得知，改善地球的環境問題是刻不容緩的，而染料敏化太陽能電池的製程與其他類型的太陽能電池相比，優勢在原料成本低、容易的製作過程，這些優點也使得許多人投入這個項目之中。

本研究分為三個部分，首先為以鐵錯合物與氧化石墨烯複合，作為對電極，研究不同的鐵錯合物與氧化石墨烯比例以提升對電極的效能，SEM分析對電極材料的表面狀態，以XPS分析材料的元素構成含量，以J-V曲線、EIS頻譜來探討其作為元件後的性能表現，Fe/GO(5:1)作為對電極，轉換效率略高Pt，達8.17%。

其次為以錳錯合物與氧化石墨烯複合，製備於對電極，研究不同的錳錯合物與氧化石墨烯比例以提升對電極的效能，TEM分析對電極材料的表面形貌，以XRD分析材料的層距變化，以EQE曲線、CV曲線來探討其作為元件後的性能表現，Mn/GO(3:1)作為對電極，轉換效率達6.64%。

本研究分第三個部分，以鋅錯合物與氧化石墨烯複合，作為對電極，研究不同的鋅錯合物與氧化石墨烯比例以提升對電極的效能，FE-SEM分析對電極材料的薄膜樣態，以XRD分析材料的層距變化，以J-V曲線、EIS頻譜來探討其作為元件後的性能表現，Zn/GO(3:1)作為對電極，達7.87%。

In recent years, we can all learn from the media, weather research and other sources that improving the earth's environmental problems is urgent, and the process of dye-sensitized solar cells has the advantages of low raw material cost and easy production process compared to other types of solar cells. These advantages have also attracted many people to this project.

This study is divided into three parts. First, iron complex and graphene oxide are composite to be used as the electrode, and the different ratios of iron complex and graphene oxide are studied to improve the performance of the electrode. SEM analysis is used to study the surface state of the electrode material, and XPS analysis is used to study the elemental composition of the material. The performance of the component is studied using J-V curve and EIS spectrum, and Fe/GO (5:1) is used as the electrode, with a conversion efficiency slightly higher than Pt, reaching 8.17%.

Secondly, manganese complex and graphene oxide are composite to be used as the electrode, and the different ratios of manganese complex and graphene oxide are studied to improve the performance of the electrode. TEM analysis is used to study the surface morphology of the electrode material, and XRD analysis is used to study the layer spacing change of the material. The performance of the component is studied using EQE curve and CV curve, and Mn/GO (3:1) is used as the electrode, with a conversion efficiency of 6.64%.

Finally, zinc complex and graphene oxide are composite to be used as the electrode, and the different ratios of zinc complex and graphene oxide are studied to improve the performance of the electrode. FE-SEM analysis is used to study the film state of the electrode material, and XRD analysis is used to study the layer spacing change of the material. The performance of the component is studied using J-V curve and EIS spectrum, and Zn/GO (3:1) is used as the electrode, with a conversion efficiency of 7.87%.

致謝 i
摘要 ii
Abstract iii
目錄 iv
圖目錄 viii
表目錄 xi
第一章 緒論 1
第二章 鐵錯合物／氧化石墨烯複合物在染料敏化太陽能電池之成效 15
第三章 錳錯合物／氧化石墨烯複合物在染料敏化太陽能電池之成效 39
第四章 鋅錯合物／氧化石墨烯複合物在染料敏化太陽能電池之成效 59
第五章 總結論 79

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